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Question

Match the List-I with List-II by using the postulates of VBT of complexes
ListIListII(p) [Ni(CN)4]2(1) sp3 hybridization(Q) [Ni(CO)4](2) dsp2 hybridization(R) [Cu(NH3)4]2+(3) μ=0 BM(S) [Pd(Cl)4]2(4) μ=1.732 BM

A
P-(3,1) Q-(1,4) R-(2,3) S-(1,4)
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B
P-(2,3)Q-(1,3) R-(1,4)S-(2,3)
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C
P-(2,4) Q-(1,4)R-(2,4)S-(2)
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D
(P-(2,3) Q-(1,3)R-(2,4)S-(2,3)
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Solution

The correct option is D (P-(2,3) Q-(1,3)R-(2,4)S-(2,3)
[Ni(CN)4]2 is with dsp2 hybridization and μ = 0 BM
[Ni(CO)4] is with sp3 hybridization and μ = 0 BM
[Cu(NH3)4]2+ is with dsp2 hybridization with μ = 1.732 BM
[Pd(Cl)4]2 is with dsp2 hybridization with μ = 0 BM

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