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Question

Match the molecules/ions (in Column-I) with their shapes (in Column-II).

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Solution

(A) ClF3 is sp3d hybridized with two lone pair of electrons. Thus, geometry is T-shaped structure with two axial and one equatorial bonds.
(B). [PCl4]+ is sp3 hybridized with tetrahedral geometry.
(C) XeF4 is sp3d2 hybridized with expected geometry octahedral but due to presence of 2 lone pairs, the geometry is square planar.
(D) XeO3 is sp3 hybridized with expected geometry is pyramidal.

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