When the compound loses its water of crystallisation on exposure to dry air then it is known as efflorescence.
Examples of efflorescent substances :
Washing soda (Na2CO3.10H2O), Glauber's salt (Na2SO4.10H2O), etc.
Certain water soluble substances, when exposed to atmosphere at ordinary temperatures, absorb moisture to form solutions and it is known as deliquescence.
Examples of deliquescent substances :
Caustic soda (NaOH), Caustic potash (KOH), etc.
Certain substances absorb moisture from the atmosphere but do not form solution when they are exposed to the same. This is known as hygroscopy.
Examples of hygroscopic substances :
Conc. Sulphuric acid (H2SO4), quicklime (CaO), etc.