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Question

Match the reactions in Column I with appropriate options in Column II.

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Solution

(ar,s,t;bt;cp,q;dr)
(ar,s,t) It is an example of electrophilic substitution reaction which results in a coupled product; hence it is coupling reaction also. It also involves carbocation intermediate.
(bt) Pinacole-pinacolone rearrangement. In this reaction, the intermediate is carbocation.
(cp,q) It is an example of addition reaction by carbonyl compounds and both enantiomers will be formed. Hence, racemic mixture will be obtained. (see diag)
(dr) It is an example of nucleophilic substitution.

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