Disproportionation or auto redox is the reaction, where one molecule of a reactant is oxidised and reduced simultaneously.
C3O2 (Fractional oxidation number).
3x−4=0⇒x=43
CH2Cl2 (Zero oxidation number).
x+2−2=0;x=0
Redox reaction:
(Mn4++2e−⟶Mn2+) (Reduction)
(2Cl⊖⟶Cl2+2e−) (Oxidation)
Photosynthesis is also a redox reaction occurring in nature.
Hence, the correct match is A→5,A→6,B→1,C→4,D→2,E→3.