(A) STATEMENT: The reaction of oxalic acid with acidified KMnO4 is first slow and then speeds up by itself. This is because one of the products of the reaction acts as a catalyst.
REASON: KMnO4 decomposes into MnO2 in sunlight.
(2) If both statement and reason are true and reason is not correct explanation of statement.
(B) STATEMENT: Anhydrous. ZnCl2 can't be made by heating ZnCl2⋅2H2O.
REASON: It undergoes hydrolysis to produce Zn(OH)2 and HCl.
(1) If both statement and reason are true and reason is correct explanation of statement
(C) STATEMENT: KMnO4 is not used as a primary standard substance. Before titration, KMnO4 is standardized by titration with appropriate primary standard.
REASON: It is deliquescent in nature.
(3) If statement is correct and reason is incorrect.
(D) STATEMENT: K2Cr2O7 has orange colour due to charge transfer.
REASON: In dichromate ion all Cr−O bonds are not identical. The Cr-O bonds of Cr-O-Cr bridge have different bond length than other Cr-O bonds due to difference in the bond order.
(4) If both statement and reason are incorrect.