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Question

Match the type of interaction in column A with the distance dependence of their interaction energy in column B:


Column 1Column 2

Ion-ion

1r

Dipole-dipole

1r3

London dispersion

1r6

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Solution

Step 1: Ion-ion

  1. The interaction energy between ions is represented by the formula E=kq1q2r where E=Energy,q1,q2=ionsandr=distance.
  2. From the formula, it is clear that Ion-ion interaction energy is inversely proportional to the distance between ions i.e E1r.

Step 2: Dipole-dipole

  1. The energy of the dipole-dipole interaction between polar molecules in solids is inversely proportional to 1r3.
  2. Dipole-dipole interaction energy1r3

Step 3: London dispersion

  1. London's dispersion forces only cover a tiny amount of ground. The distance to the power of six between two interacting particles is inversely proportional to the interaction energy.
  2. London dispersion interaction energy1r6

Hence, AI,BII,CIII.


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