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Question

FeSO4 forms brown ring with:

A
NO3
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B
NO
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C
NO2
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D
N2O3
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Solution

The correct option is B NO
The brown ring test is used to detect the presence of NO (nitrate) ion. This is a three-step reaction at the end of which Fe and NO form a deep brown coloured complex called iron nitrososulphate (FeSO4.NO).

The reactions involved in the brown ring test are as follows:

1. NaNO3+H2SO4NaHSO4+HNO3

2. 2HNO3+6FeSO4+3H2SO43Fe2(SO4)3+2NO+4H2O

3. FeSO4+NOFeSO4.NO



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