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Question

Maximum bond angle is present in:

A
BBr3
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B
BCl3
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C
BF3
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D
none of these
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Solution

The correct option is A BBr3
Boron halides show sp2 hybridisation but due to electronegativity difference between halides, the bond angle will show variations
Bond anvle of any molecule is inverely proportional to the electronegativity of surrounding atoms i.e., lesser the electronegativity of attached atoms than more is the bond angle
So the order of electronegativity of halides are
F>Cl>Br
order of bond angle is BBr3>BCl3>BF3
Ans is BBr3

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