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Question

Me3C−O||C−18O−CMe3dilH2SO4−−−−−−→
Product of this reaction and the mechanism is:

A
Me3CO||COH+Me3C18OH,AAC1
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B
Me3CO18||COH+Me3C18OH,AAL1
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C
Me3CO||COH+Me3C18OH,AAC2
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D
Me3CO||C18OH+Me3C18OH,AAL2
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Solution

The correct option is B Me3CO18||COH+Me3C18OH,AAL1
Me3CO||C18OcMe3dil.H2SO4−−−−−Me3cO||COH+Me3C18OH
The reactant with dilute sulphuric acid to produce 1 molecule of Tert-butyl hydroperoxide. O18 is levelled from attached to Tert-butyl alcohol.

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