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Question

Metal carbonates decompose on heating to give metal oxide and carbon dioxide. Which of the metal carbonates is most stable thermally?

A
MgCO3
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B
CaCO3
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C
SrCO3
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D
BaCO3
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Solution

The correct option is D BaCO3
BaCO3 is most thermally stable as the size of Ba2+ is big due to which it is having low polarising power and thus cannot polarize oxygen electrons due to which carbonates of large cations are stable.

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