Metal element 'M' of radius 50nm is crystallized in FCC format and made into cubical crystals such that face of unit cells are aligned with face of cubical crystal.If total number of metal atoms of 'M' at face of cubical crystal is 6 × 1030, then area of one face of cubical crystal is A × 1016 m2, the value of 'A' is:
Consider the unit cell face
So, atoms of Face will be = 4 × 18 + 12 × 1 = 1 atoms no. of atoms at one face of crystal = 16 × 1030
= 1030 atoms. So, no. of units cells of edge of crystal = √1030 = 1015
Now edge length of one unit cell = 4√2 × 50 × 1015nm
So, area of face of crystal = (4√2×50×1015)2 nm2
= 162 × 25 × 102 × 1030 = 2 × 1034 nm2
= 2 × 1034 × 10−18m2 = 2×1016m2.