Metal hydrides are iconic, covalent or molecular in nature. Amoung LiH,NaH,KH,RbH,CsH, the coorect order of increasing ionic character is
A
LiH>NaH>CsH>KH>RbH,
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B
NaH>CsH>RbH>KH>LiH
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C
RbH>CsH>NaH>KH>LiH
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D
LiH<NaH<KH<RbH<CsH
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Solution
The correct option is DLiH<NaH<KH<RbH<CsH According to Fajan's rule, polarising power decreases with increse in size of cation and hence covalent character decreases, Ionic character increases with decrease in covalent character. So, ionic character increases with increase in size of caption.
As we move down the group, the size of elements increases.
Thus, the order of atomic radii of the alkali metals isLi<Na<k<Rb<Cs.
Thus, order of increasing percentage ionic character in alkali metal hydrides will be: LiH<NaH<KH<RbH<CsH