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Question

MetalElectrode potential(V)
Cu2+0.34
Ag+0.80
Au3+1.50
Which metal ion will act as the best oxidizing agent?

A
Cu2+
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B
Ag+
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C
Au3+
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D
None of these
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Solution

The correct option is B Au3+
According to the electrochemical series, metals lying towards the bottom of the series have high value of positive standard electrode potential. These metals can easily accept electrons. Hence the metals at the bottom of the series are good oxidizing agents.
Among the above mentioned metal ions, Au3+ has the highest positive standard electrode potential. Hence Au3+ can most easily accept electrons. Hence it is the best oxidizing agent.

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