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Question

Metallic magnesium has a hexagonal close-packed structure and a density of 1.74 g/cm2. Assume magnesium atoms to be spheres of radius r. 74.1% of the space is occupied by atoms. Calculate the volume of each atom and the atomic radius r. (Mg=24.31)

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Solution

Atomic mass =54.94
density =7.42g/cc
Apparent volume occupied by one atom =?
volume=massdensity=54.947.42=7.40cm3 (volume of one mole)
volume of one atom =volume of one mole6.022×1023
=7.406.022×1023
=1.23×1023cm3

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