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Question

Methane reacts with chlorine in the presence of sunlight. If this reaction is allowed to continue, the end product formed will be :

A
carbon tetrachloride
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B
chloroform
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C
ethylene chloride
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D
chalcogons
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Solution

The correct option is A carbon tetrachloride
When methane reacts with chlorine in presence of sunlight, it undergoes chlorination to form methyl chloride.

CH4+Cl2hvCH3Cl+HCl

This reaction go on further to produce polyhalogen derivative of alkane until all the hydrogen atom on methane is replaced by the corresponding number of the chlorine atom.

CH3Cl+Cl2hvCH2Cl2+HCl

CH2Cl2+Cl2hvCHCl3+HCl

CHCl3+Cl2hvCCl4+HCl

Hence , Carbon tetrachloride is the end product .

Therefore , option A is correct .

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