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Question

Methane reacts with chlorine in the presence of sunlight. What is the name of this reaction?

A
substitution reaction
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B
acid base reaction
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C
addition reaction
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D
double displacement reaction
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Solution

The correct option is A substitution reaction
Methane reacts with chlorine in the presence of sunlight, it is an example of a substitution reaction is also called halogenation. When chlorine gas (ClCl) is irradiated, some of the molecules are split into two chlorine radicals (Cl) whose free electrons are strongly nucleophilic. One of them breaks a weak CH covalent bond and grabs the liberated proton to form the electrically neutral HCl. The other radical reforms a covalent bond with the CH3to form CH3Cl.
CH4+Cl2SunlightCH3Cl+HCl
CH3Cl+Cl2SunlightCH2Cl2+HCl
CH2Cl2+Cl2SunlightCHCl3+HCl
CHCl3+Cl2SunlightCCl4+HCl
Option A is correct.

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