The correct option is A substitution reaction
Methane reacts with chlorine in the presence of sunlight, it is an example of a substitution reaction is also called halogenation. When chlorine gas (Cl−Cl) is irradiated, some of the molecules are split into two chlorine radicals (Cl) whose free electrons are strongly nucleophilic. One of them breaks a weak C−H covalent bond and grabs the liberated proton to form the electrically neutral HCl. The other radical reforms a covalent bond with the CH3to form CH3Cl.
CH4+Cl2Sunlight→CH3Cl+HCl
CH3Cl+Cl2Sunlight→CH2Cl2+HCl
CH2Cl2+Cl2Sunlight→CHCl3+HCl
CHCl3+Cl2Sunlight→CCl4+HCl
Option A is correct.