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Question

Methyl cyanide on reaction with sodium and C2H5OH forms:

A
ethyl amine
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B
ethanoic acid
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C
ethanimine
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D
none of these
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Solution

The correct option is A ethyl amine
Methyl cyanide on reaction with sodium and ethanol forms ethylamine.
CH3CN+4[H]Na/ethanol−−−−−−CH3CH2NH2
In this reaction, the nitrile group is hydrogenated to form a primary amine. This is a useful method to increase the length of a carbon chain in preparing a primary amine which contains one more carbon atom than the alkyl halide from which alkyl cyanide is obtained.

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