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Question

Methyl cyanide on reaction with sodium and C2H5OH forms :

A
ethylamine
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B
ethanoic acid
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C
ethanimine
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D
none of the above
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Solution

The correct option is A ethylamine
Methylcyanide on reaction with sodium and ethonol forms ethylamine.

CH3CN+4[H]Na/ ethanol−−−−−−CH3CH2NH2

In this reaction, the nitrile group is hydrogenated to form a primary amine. This is a useful method to increase the length of a carbon chain in preparing a primary amine which contains one more carbon atom than the alkyl halide from which alkyl cyanide is obtained.

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