Methylene blue is adsorbed on activated charcoal from its aqueous solution at 25∘C. For this process, the correct statement is:
A
The adsorption requires activation at 25∘C
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B
The adsorption is accompanied by a decrease in enthalpy
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C
The adsorption increases with an increase in temperature
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D
The adsorption is irreversible
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Solution
The correct option is B The adsorption is accompanied by a decrease in enthalpy This is physisorption which is spontaneous at room temperature. It is an exothermic process. So, ΔH<0. Exothermic reactions are favoured at low temperatures. Physcial adsorption is always reversible.