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Byju's Answer
Standard XII
Chemistry
Structure of Amines & Optical Activity
MF + Xe F4→ '...
Question
M
F
+
X
e
F
4
→
'A'
(
M
+
=
Alkali metal cation
)
The state of hybridisation of the central atom in 'A' and shape of the species are :
A
s
p
3
d
, TBP
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B
s
p
3
d
3
, distorted octahedral
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C
s
p
3
d
3
,pentagonal planar
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D
No compound formed at all
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Solution
The correct option is
C
s
p
3
d
3
,pentagonal planar
Here,
M
2
X
e
F
6
forms as product, which has
s
p
3
d
3
hybridization and pentagonal planar structure.
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Similar questions
Q.
Structure and hybridisation of
I
F
7
Q.
The correct order of hybridization of the central atoms in the following species
X
e
F
2
,
X
e
F
+
3
,
X
e
F
4
,
X
e
F
6
Q.
In
s
p
3
d
3
hybridisation, which orbitals are involved?
Q.
Identify the correct match.
(i)
X
e
F
2
(a)
Central atom is
s
p
3
hybridised and has a bent shape.
(ii)
N
−
3
(b)
Central atom is
s
p
3
d
2
hybridised and has an octahedral shape.
(iii)
P
C
l
−
6
(c)
Central atom is
s
p
hybridised and has a linear shape.
(iv)
I
C
l
+
2
(d)
Central atom is
s
p
3
d
hybridised and has a linear shape.
Q.
In the valence bond theory, hybridization of orbitals is an integral part of the bond formation. Hybridisation consists of mixing or a linear combination of the "pure" atomic orbitals in such a way as to form new hybrid orbitals such as
s
p
,
s
p
2
,
s
p
3
,
s
p
3
d
,
s
p
3
d
3
, etc.
Which of the following atomic orbitals does not participate in trigonal bipyramidal hybridization i.e.
s
p
3
d
hybridization?
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