Minimum amount of Ag2CO3 (s) required to produce sufficient amount of oxygen for the complete combustion of C2H2 which produces 11.2 L of CO2 at STP after combustion is_________. Ag2CO3(s)→2Ag(s)+CO2(g)+12O2(g) C2H2+52O2→2CO2+H2O
A
276 g
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B
345 g
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C
690 g
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D
1380 g
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Solution
The correct option is B345 g 11.2 L of CO2 at STP = 11.2 L 22.4 L/mol = 0.5 mol 2 moles of CO2=52 moles of O2 required for the complete combustion of C2H2.
1 mole of CO2=52×2 moles of O2 required for the complete combustion of C2H2.
0.5 mol of CO2= 0.5 mol×52×2=58 moles of O2 required for the complete combustion of C2H2.
12 moles of O2=1 mole of Ag2CO3(s)
required.
1 moles of O2=2 mole of Ag2CO3(s)
required.
58 moles of O2=2×58=54 moles of Ag2CO3(s) required. The molar mass of Ag2CO3(s)=275.75 g/mol. The mass of Ag2CO3(s) required =275.75 g/mol ×54 mol =345 g.