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sp3 Hybridisation

Minimum bond ...

Question

Minimum bond angles is present in:

{C O}_{2}

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{S O}_{2}

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{S O}_{4}^{- 2}

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{S O}_{3}

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Solution

The correct option is C ${S O}_{4}^{- 2}$
A. $C O_{2}$ has $s p$ hybridisation. So bond angle must be 180 $^{\circ}$ .
B. $S O_{2}$ and $S O_{3}$ both are $s p^{2}$ hybridised . So bond angle must be in the range of 120 $^{\circ}$ .
C. $S O_{4}^{- 2}$ is $s p^{3}$ hybridised. So the bond angle must be in the range of $109^{\circ}$ .
So, the correct option is C

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Similar questions

The rates of diffusion of $S O_{2}, C O_{2}, P C l_{3} a n d S O_{3}$ are in the following order –

S O_{2}

119^{\circ}

S O_{3}

120^{\circ}

S

S O_{2}

S O_{3}

s p^{2}

S O_{2}

119^{o}

S O_{3}

120^{o}

S

S O_{2}

S O_{3}

s p^{2}

d π - p π

S O_{2}, S O_{3}, C l O_{4}^{-}

S + O_{2} \to {S O}_{2}; Δ H = - 298.2 k J

{S O}_{2} + \frac{1}{2} O_{2} \to S O_{3}; Δ H = - 98.7 k J

{S O}_{3} + H_{2} O \to H_{2} {S O}_{4}; Δ H = - 130.2 k J

H_{2} + \frac{1}{2} O_{2} \to H_{2} O; Δ H = - 227.3 k J

H_{2} {S O}_{4}

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