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Question

Mixture X reacts with 0.02 mol of [Co(NH3)5SO4]Br, 0.02 mol of [Co(NH3)5Br]SO4 was prepared in 2 litre of solution.
1 litre of mixture X+ excess AgNO3 Y.
1 litre of mixture X+ excess BaC12Z
Number of moles of Y and Z are :

A
0.01, 0.01
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B
0.02, 0.01
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C
0.01, 0.02
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D
0.02, 0.02
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Solution

The correct option is A 0.01, 0.01
Option (A) is correct.

No. of moles of Y and Z are 0.01 mol and 0.01 mol respectively.
Mixture X contains 0.02 mol of two species in 2 litre of solution,so the concentration of each in solution is 0.01 mol/lit.

[Co(NH3)5SO4]Br(0.01mol/lit)+AgNO3[Co(NH3)5SO4]NO3+AgBr(Y,0.01mol/lit)

[Co(NH3)5Br]SO4(0.01mol/lit)+BaCl2[Co(NH3)5Br]Cl2+Ba2SO4(Z,0.01mol/lit)

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