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Byju's Answer
Standard X
Chemistry
Mole Concept and Avogadro's Number
mixture of SO...
Question
mixture of SO3, SO2 and O2 gases is maintained at equilibrium in 10 litre flask at a temp in which Kc for the reaction 2SO2 + O2 gives 2SO3. Kc= 100 .at equilibrium-
1. if no. of moles of SO3 and SO2 in flask are same then how many moles of O2 are present.
2.no. of moles of SO3 is twice of SO2, then how many moles of O2 are present.
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Solution
1. We know,at equilibrium ,
K
c
=
[
S
O
3
]
2
[
S
O
2
]
2
[
O
2
]
=
100
As moles of SO
2
is equal to that of SO
3
,
[SO
2
] = [SO
3
]
[O
2
] =
1
100
m
o
l
e
s
o
f
S
O
3
m
o
l
e
s
o
f
S
O
2
=
2
W
e
a
g
a
i
n
h
a
v
e
,
K
c
=
[
S
O
3
]
2
[
S
O
2
]
2
[
O
2
]
=
100
(
m
o
l
e
s
o
f
S
O
3
m
o
l
e
s
o
f
S
O
2
)
2
(
10
m
o
l
e
s
o
f
O
2
)
=
100
2
2
×
10
m
o
l
e
s
o
f
O
2
=
100
m
o
l
e
o
f
O
2
=
0
.
4
M
o
l
e
o
f
O
2
10
=
1
100
(
v
o
l
=
10
L
)
M
o
l
e
o
f
O
2
=
0
.
1
2. Further,if moles of SO
3
are twice that of SO
2
,
Suggest Corrections
1
Similar questions
Q.
A mixture of
S
O
3
,
S
O
2
and
O
2
gases are maintained at equilibrium in 10 litre flask at a temperature at which
K
c
for the reaction,
2
S
O
2
(
g
)
+
O
2
(
g
)
⇔
2
S
O
3
(
g
)
is 100
m
o
l
−
1
litre.
At equilibrium,
a) If no of mole of
S
O
3
and
S
O
2
in the flask are same, how many moles of
O
2
are present?
b) If no. of mole of
S
O
3
in the flask are twice the no of mole of
S
O
2
, how many moles of
O
2
are present?
Q.
Homogeneous equilibrium :
K
c
is gaseous system
A mixture of
S
O
3
,
S
O
2
and
O
2
gases is maintained at equilibrium in
10
litre flask at a temperature at which
K
c
for the reaction,
2
S
O
2
(
g
)
+
O
2
(
g
)
⇌
2
S
O
2
(
g
)
is
100
m
o
l
−
1
litre. At equilibrium.
(a) If no. of mole of
S
O
3
and
S
O
2
in flask are same, how many mole of
O
2
are present?
(b) If no. of mole of
S
O
3
in flask are twice the no. of mole of
S
O
2
, how many mole of
O
2
are present?
Q.
A mixture of
S
O
3
,
S
O
2
and
O
2
gases is maintained in a
10
L
flask at a temperature at which the equilibrium constant for the reaction is
100
and the reaction is,
2
S
O
2
(
g
)
+
O
2
(
g
)
⇌
2
S
O
3
(
g
)
.
(i) If the number of moles of
S
O
2
and
S
O
3
in the flask are equal, how many moles of
O
2
are present?
(ii) If the number of moles of
S
O
3
in the flask is twice the number of moles of
S
O
2
, how many moles of oxygen are present?
Q.
A mixture of
S
O
3
,
S
O
2
and
O
2
gases is maintained in a
10.0
L
flask at a temperature at which equilibrium constant
K
c
fo the reaction
2
S
O
2
(
g
)
+
O
2
(
g
)
⇌
2
S
O
3
(
g
)
is
100
Then choose the correct statements :
Q.
At 800 K a reaction mixture contained 0.5 mole of
S
O
2
. 0.12 mole of
O
2
and 5 mole of
S
O
3
at equilibrium.
K
c
for the equilibrium
2
S
O
2
+
O
2
⇌
2
S
O
3
is 833 lit/ mole. If the voiume of the container is 1 litre, calculate how much
O
2
is to be added at this equilibrium in order to get 5.2 moles of
S
O
3
at the same temperature.
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