The correct option is C 4R
For a non-linear triatomic gas, it can have degree of freedom as as translational (3), rotational (2), vibrational (1).
f=3A−B
For non-linear triatomic, A=3 and B=3
⇒Total degree of freedom will be, f=6
Since,
Cp=(f2+1)R
∴Cp=(62+1)R=4R