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Question

Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP : 1 atmospheric pressure, 0oC). Show that it is 22.4 litres.

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Solution

The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV = nRT
Where,
R is the universal gas constant =8.314Jmol1K1
n = Number of moles = 1
T = Standard temperature = 273 K
P = Standard pressure = 1 atm =1.013×105Nm2
V=nRT/P
=1×8.314×273/(1.013×105)
=0.0224m3
=22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.

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