Density of water in g/ml is 1. It is a standard value
However for doing the problem we do not require density value and hence the statement is not necessary.
Given
Mole fraction of A = 0.2
decimal 0.2 is same as fraction
.
Mole fraction of A =
And here the mixture contains A and
Therefore
mole fraction of
That is if we take 5 moles of mixture we have
moles of A and
moles of
Moles =
Molar mass of water is 18
4 moles of water means it weigh 72g or 72mL (since 1g = 1mL)
1 mole of A is present in 72 mL of water.
Molarity is no. of moles of solute present in 1 L of solution.
1 mL =
72 mL=
So molarity =
= 13.9 M