Given that the mole fraction of ethanol-water system is 0.25
i.e. solution contains 0.25 mol EtOH and 0.75 mol H2O
Mol wt of EtOH is 46.06 g/mol
Therefore 0.25 mol = 11.515 g of EtOH
Mol wt of H2O is 18.01528 g/mol
There fore 0.75 mol = 13.51 g of H2O
Total weight = 25.02646 gms
Wt % of EtOH is
11.515 / 25.02646 x 100
= 46.011 %