The correct option is A Ethane
Bond length order - sp−sp<sp2−sp2<sp3−sp3
So, the carbon-carbon atoms bond in each of these molecules can be analyzed as:
A: CH3−CH3 sp3−sp3 bond
B: CH2=CH2 sp2−sp2 bond
C: CH≡CH sp−sp bond
D: C6H6 sp2−sp2 bond
Based on the bond length order, (a) has largest distance between the two adjacent carbon atoms.