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Question

Molten AlCl3 is electrolysed with a current of 0.5 ampere to produce 27 g Al. The number of electrons are used are xNA. The value of x is :

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Solution

Al3++3eAl

From Faraday's law of electrolysis, we know that

w=EQ96500.

E=27/3=9.

Q96500=27/9=3F.

One Farad is the charge on 1 mole of electrons. Hence 3NA electrons are used.

So, the value of x is 3

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