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Question

Monochromatic radiation emitted when electron on hydrogen atom jumps from first exited to the grounds state irradiates a photosnesitive material. The stopping potential is measured to be 3.57V. The threshold frequency of the material is :

A
1.6×1015Hz
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B
2.5×1015Hz
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C
4×1015Hz
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D
5×1015Hz
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Solution

The correct option is A 1.6×1015Hz
For hydrogen atom,

En=13.6n2eV

For ground state, n=1

E1=13.612=13.6eV

For first excited state, n=2

E2=13.622=3.4eV

The energy of the emitted photon when an electron jumps from first excited state to ground state is,

hν=E2E1

=3.4eV(13.6eV)=10.2eV

Maximum kinetic energy,

Kmax=eVs=e×3.57V=3.57eV

According to Einstein's photoelectric equation,

Kmax=hνϕ0

where, ϕ0 is the work function and hν is the incident energy

ϕ0=hνKmax

=10.2eV3.57eV=6.63eV

Threshold frequency,

ν0=ϕ0h=6.63×1.6×1019J6.63×1034Js=1.6×1015Hz

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