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Question

Monochromatic radiation of wave-length λ is incident on a hydrogen sample in ground state. Hydrogen atoms absorb a fraction of light and subsequently emit radiations of six different wavelengths. Find the wavelengths λ.

A
975 A
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B
1218 A
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C
2248 A
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D
4316 A
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Solution

The correct option is A 975 A
Equating 6 with n(n1)/2, we get n=4
it means after absorbing the photon the hydrogen had gotten the state n=4 subsequently after deexcitation
it emitted 6 spectral lines.
Now energy of state n=4 is E4=13.6/42=0.85eV
Where13.6eV=E1
So the energy difference=13.60.85=12.75eV
If wavelength be λ then λ=hcE(eV)nm=1242.312.75nm=97.43nm=974.3A
Option A is correct.

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