Monochromatic radiation of wave-length λ is incident on a hydrogen sample in ground state. Hydrogen atoms absorb a fraction of light and subsequently emit radiations of six different wavelengths. Find the wavelengths λ.
A
975A
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B
1218A
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C
2248A
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D
4316A
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Solution
The correct option is A975A Equating 6 with n(n−1)/2, we get n=4
it means after absorbing the photon the hydrogen had gotten the state n=4 subsequently after de−excitation
it emitted 6 spectral lines.
Now energy of state n=4 is E4=−13.6/42=−0.85eV
Where−13.6eV=E1
So the energy difference=13.6−0.85=12.75eV
If wavelength be λ then λ=hcE(eV)nm=1242.312.75nm=97.43nm=974.3A