More volatile liquid from a liquid-liquid mixture of miscible liquids undergoes ____ on heating.
condensation after vaporisation
To separate a mixture of two or more miscible liquids, distillation (when the difference between the boiling points of liquids is more than 25 ∘C) or fractional distillation (when the difference between the boiling points of liquids is less than 25 ∘C) are used. In both, the processes the liquid with lower boiling point vaporises and then it is condensed.
So, the volatile liquid undergoes condensation after vaporisation.