MSO4NH4OH−−−−−→↓XwhiteNH4OH−−−−−→excessYH2S−−→↓Z. Here M and Z are:
Cu, ZnS
Zn, ZnS
Fe, FeS
Al, Al2S3
ZnSO4NH4OH−−−−−→Zn(OH)2White ppt↓NH4OH−−−−−→[Zn(NH3)4]2+Soluble complex(aq)H2S−−→ZnS↓White ppt
For cell reaction, Zn+Cu2+→Zn2++Cu, cell representation is