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Question

N(<100) molecules of a gas have velocities 1,2,3 ....N/km/s respectively. Then:

A
rms speed and average speed of molecules is same
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B
ratio of rms speed to average speed is (2N+1)(N+1)/6N
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C
ratio of rms speed to average speed is (2N+1)(N+1)/6
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D
ratio of rms speed to average speed of a molecule is 2/6x(2N+1)/(N+1)
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Solution

The correct option is D ratio of rms speed to average speed of a molecule is 2/6x(2N+1)/(N+1)
As we know, sum of the first n natural numbers is n[n+1]/2 and sum of the squares of first n natural numbers is n[n+1][2n+1]/6.
So urms=n[n+1][2n+1]/6n and uavg=n[n+1]/2n.
So, ratio of rms speed to average speed of a molecule is 2/6x(2N+1)/(N+1).
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