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Question

N2(g) and H2(g) are taken in a vessel in mass ratio of 7:1. The only reaction, N2+2H2N2H4(g) occurs. Pressure due to N2H4 at equilibrium is 0.2 times of total pressure 'P'. Then at equilibrium.

A
Partial pressure of N2=2P/15
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B
Partial pressure of H2=8P/25
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C
2pN2=pH2
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D
PN2=2pH2
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Solution

The correct option is C 2pN2=pH2
The gases are taken in mass ratio of 7:1.
N2+2H2N2H4
t=0 P 2P 0
t=equilibrium Pα (2P2α) α
Here, α=0.2P

where,

P is Total Pressure
PN2=0.8P
PH2=1.6P
PH2=2PN2
Hence, option (C) is correct.

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