Which of the following reaction is an example of ammonolysis ?

C_{6} H_{5} N H_{2} H C l - - \to C_{6} H_{5} N H_{3}^{+} C l^{-}

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C_{6} H_{5} C H_{2} C N [H] - - \to C_{6} H_{5} C H_{2} C H_{2} N H_{2}

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C_{6} H_{5} C O C l + C_{6} H_{5} N H_{2} \to C_{6} H_{5} C O N H C_{6} H_{5}

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C_{6} H_{5} C H_{2} C l + N H_{3} \to C_{6} H_{5} C H_{2} N H_{2}

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Solution

The correct option is D $C_{6} H_{5} C H_{2} C l + N H_{3} \to C_{6} H_{5} C H_{2} N H_{2}$
(a) Ammonolysis of alkyl halides is the reaction of alkyl halide with $N H_{3}$ which leads to the prepartion of amines.
It is a nucleophilic substitution reaction.
$C_{6} H_{5} C H_{2} C l + N H_{2} \to C_{6} H_{5} C H_{2} N H_{2}$

(b) In this reaction, aniline react with acid to form ammonium salt.

(c). It is a nucleophilic addition reaction.

(d). It is the reduction reaction of nitrile to amine.

Hence, option (a) is correct.

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