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Question

Match the compounds given in List-I with List-II and select the suitable option using the code given below :

List -I List-II
(A) Benzaldehyde (i) Phenolphthalein
(B) Phthalic anhydride (ii) Benzoin
condensation
(C) Phenyl benzoate (iii) Oil of wintergreen
(D) Methyl salicylate (iv) Fries
rearrangement

Code :
(A) (B) (C) (D)

A
(iv) (i) (iii) (ii)
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B
(ii) (iii) (iv) (i)
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C
(ii) (i) (iv) (iii)
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D
(iv) (ii) (iii) (i)
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Solution

The correct option is C (ii) (i) (iv) (iii)
(a)
(b)
(c) The fries rearrangement enables the preparation of acylphenols. The reaction is catalysed by Bronsted or lewis acid such as AlCl3
(d)
Hence, option (d) is correct.

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