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Chemical Properties of Ethers

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Question

The compound A on treatement with Na gives B, and with $P C l_{5}$ gives C. B and C react together to give diethyl ether. A, B and C are in the order

A

C_{2} H_{5} O H, C_{2} H_{5} O N a, C_{2} H_{5} C l

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B

C_{2} H_{5} C l, C_{2} H_{6}, C_{2} H_{5} O H

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C

C_{2} H_{5} O H, C_{2} H_{5} C l, C_{2} H_{5} O N a

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D

C_{2} H_{5} O H, C_{2} H_{6}, C_{2} H_{5} C l

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Solution

The correct option is A $C_{2} H_{5} O H, C_{2} H_{5} O N a, C_{2} H_{5} C l$
Ethanol with $N a$ form sodium ethoxide and with $P C l_{5}$ it forms ethyl chloride. Ethoxide undergoes nucleophilic substitution reaction with ethyl chloride.

So, the correct option is (c).

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