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Question

NiS on reacting with aqua regia gives

A
NiSO4
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B
NiNO3
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C
NiCl2
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D
Ni(OH)2
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Solution

The correct option is C NiCl2
NiS (black precipitate) from group IV analysis dissolves in aqua regia to give nickel chloride which is soluble in water.

3NiS+2HNO3+6HCl3NiCl2+2NO+3S+4H2O

When dimethyl glyoxime is added ​to the aqueous solution of nickel ​chloride made alkaline by ​adding NH4OH solution​ it gives a brilliant red precipitate.

Option (b) is correct.

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