The correct option is C NiCl2
NiS (black precipitate) from group IV analysis dissolves in aqua regia to give nickel chloride which is soluble in water.
3NiS+2HNO3+6HCl→3NiCl2+2NO+3S+4H2O
When dimethyl glyoxime is added to the aqueous solution of nickel chloride made alkaline by adding NH4OH solution it gives a brilliant red precipitate.
Option (b) is correct.