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Question

Main products formed during a reaction of 1-methoxy naphthalene with hydroiodic acid are :

A
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B
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C
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D
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Solution

The correct option is A
Ethers can be reactive under ​drastic reaction conditions (high temperature, high concentration) due to the cleavage of the C-O bond.​
In first step of the reaction, protonation of ether (O) group take place.
In second step, SN2 reaction take place, where I nucleophile will attack the less hindered site to form methyl iodide and naphthol.


Hence, option (c) is correct.

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