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Question

'n' moles of a non electrolyte are added to 'N' moles of solvent. The addition causes a lowering in vapour pressure of solvent by 20%. The ratio of moles of solvent and its solute is :

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Solution

The expression for the relative lowering of vapor pressure is P0PP0=nn+N
The lowering in vapor pressure of the solvent is 20%.
Hence, 10080100=nn+N
20100=nn+N
20n+20N=100n
20N=80n
Nn=8020=4
Thus, the ratio of the moles of the solvent and solute is 4.

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