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Question

Na2S+Na2[Fe(CN)5NO]X(purplecolor)
Find the value of magnetic moment of X.

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Solution

here X is,
Na4[Fe(CN)5(NOS)]
+2
so Fe+2=d6 , due to strong ligand pairing happens and low spin complex forms.
So it have zero unpaired electron and zero magnetic moment.
Fe=d2sp3 hybridization so two d-orbitals involved in hybridization.
which have 6 ligands.
and two ambidentate ligands.
354387_309592_ans.jpg

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