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Question

Na2SO3 and Na2S2O3 cannot be distinguished by:

A
addition of Pb(OAc)2 followed by heating
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B
addition CaCl2 solution
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C
addition of AgNO3 followed by heating
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D
all of these
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Solution

The correct option is B addition CaCl2 solution
A) Na2S2O3+Pb(CH3COO)2Na(CH3COO)+PbS2O3


B) CaCl2+Na2SO3CaSO3+2NaCl

CaCl2+Na2S2O3CaSO3+NaCl

C) 2AgNO3+Na2SO3Ag2SO3+2NaNO3

2AgNO3+Na2S2O3Ag2S2O3+2NaNO3

Hence , option B is correct .

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