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Question

NaCl(aq) gives a white precipitate with AgNO3 solution but CCl4 or CHCl3 does not, because:

A
NaCI is a covalent compound and forms AgCl as white ppt
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B
NaCl is an ionic compound and forms AgCl as white ppt
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C
CCl4 and CHCl3 are ionic compound
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D
none of these
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Solution

The correct option is B NaCl is an ionic compound and forms AgCl as white ppt
NaCl being an ionic compound and thus reacts with AgNO3(aq) to give ionic reaction, forming AgCl as white ppt. CCl4 and CHCl3 being covalent do not furnish Cl ions in solution.
NaCl+AgNO3AgCl+NaNO3

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