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Question

Name of the group-16 element which shows maximum catenation.

A
Oxygen
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B
Sulphur
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C
Selenium
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D
Tellurium
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Solution

The correct option is A Sulphur
The greater the element-element bond strength, the higher is the tendency towards catenation.
As the size increases from S to Te, the bond dissociation energy decreases. O - O bond energy is, however, smaller than that of S-S because of inter electronic repulsions within the smaller size of oxygen atoms.

Thus, sulphur has a maximum tendency towards catenation.

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