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Question

Name the compound D.

A
Fe(OH)2
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B
FeO
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C
Fe2O3
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D
Fe3O4
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Solution

The correct option is C Fe2O3
A light-green crystalline solid is expected to be ferrous sulphate. There is no reaction with dilute sulphuric acid. With potassium permanganate, ferrous sulphate is oxidized to ferric sulphate and the pink color disappears. On strong heating, it gives two gases which are two oxides of sulphur, along with a brown residue, ferric oxide. When gases are passed through acidified potassium dichromate, it is reduced by sulphur dioxide to give a green solution of chromium sulphate. On adding barium sulphate, the green solution of sulphate gives a white precipitate of barium sulphate. In charcoal cavity test, ferric oxide is reduced to iron which is magnetic.
FeSO4+dilNoreaction
FeSO4+KMnO4H2SO4−−−Fe2(SO4)3+Mn2+(Pink)(Colorless)
FeSO4ΔFe2O3+SO2+SO3
K2Cr2O7+SO2H2SO4−−−Cr2(SO4)3Green
H2O+SO3H2SO4
H2SO4+Ba(NO3)22HNO3+BaSO4White

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