(1) (C2H5)2NH and CH3−NH−C3H7 shows metamerism. They differ in the nature of alkyl group attached to N atom.
(2) 1−butanol and 2 methyl−1− propanol show chain isomerism. They differ in the carbon skeleton / alkyl chain. One is straight chain (1-butanol) and other is branched (2 methyl−1− propanol).