The correct option is A cis-polyisoprene and trans-polyisoprene
Natural rubber and gutta-percha respectively, are cis-polyisoprene and trans-polyisoprene.
Isoprene is 2-methyl-1,3-butadiene.
Natural rubber has long flexible chains, weak intermolecular forces and exhibits elastic properties.
Gutta-percha has zigzag chains fitting in one another. It is non elastic and crystalline.